{Bis[2-(diphenylphosphanyl)ethyl]phenylphosphane-κ3 P,P′,P′′}[(Z)-8-mesitylcyclooct-4-en-1-yl]platinum(II) tetrafluoridoborate dichloromethane disolvate
نویسندگان
چکیده
In the title ionic compound, [Pt(C(17)H(23))(C(34)H(33)P(3))](BF(4))·2CH(2)Cl(2), the Pt(II) atom adopts a square-planar coordination geometry with the large (Z)-8-mesityl-cyclo-oct-4-en-1-yl group occupying the fourth coordination site. The (triphos)Pt moiety and the mesityl group are attached to the cyclo-oct-4-ene motif at the 1- and 8-position in a syn configuration. The (BF(4))(-) anion and one of the dichloromethane solvate molecules each are disordered over two sets of sites.
منابع مشابه
[1,1′-Bis(diphenylphosphanyl)ferrocene-κ2 P,P′]dichloridocadmium(II) dichloromethane disolvate
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عنوان ژورنال:
دوره 67 شماره
صفحات -
تاریخ انتشار 2011